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Die Thermolumineszenz dient dabei als Ergänzung zur Radiokohlenstoffdatierung (auch: C14-Datierung), insbesondere dort, wo Datierungen jenseits der begrenzten Reichweite der C14-Datierung benötigt werden oder wo kein organisches Material zur Verfügung steht. Dabei werden Elektronen in „Elektronenfallen“ zwischen Valenz- und Leitungsband festgesetzt. Beim Erhitzen emittieren Körper mit steigender Temperatur zunächst Wärmestrahlung, die dann auch den sichtbaren Spektralbereich beinhaltet.

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Diese hängt von der Intensität und der Zeitdauer der vorhergehenden angesammelten Energie ab.

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